天然产物研究与开发 ›› 2017, Vol. 29 ›› Issue (增刊1): 11-17.doi: 10.16333/j.1001-6880.2017.S.003

• 研究论文 • 上一篇    下一篇

傣药石梓皮和接骨草的化学成分研究

李宁新1,2,范青飞1,宋启示1*   

  1. 1中国科学院西双版纳热带植物园 热带植物资源可持续利用重点实验室,昆明 650223;2中国科学院大学,北京 100049
  • 出版日期:2017-08-02 发布日期:2017-08-02

Chemical Constituents from Bark of Gmelina arborea and Sambucus chinensis

LI Ning-xin1,2,FAN Qing-fei1,SONG Qi-shi1*   

  1. 1Laboratory of Tropical Plant Resources and Sustainable Use,Xishuangbanna Tropical Botanical Garden,Chinese Academy of Science,Kunming 650223,China;2Univercity of Chinese Academy of Science,Beijing 10049,China
  • Online:2017-08-02 Published:2017-08-02

摘要: 采用色谱法从傣药石梓皮(1)和接骨草(2)中分别得到9个和17个化合物,利用波谱学方法鉴定了它们的结构。从石梓皮得到:芹菜素(1-1)、棕榈酸(1-2)、specioside 6′-O-α-D-galactopyranoside (1-3)、豆甾醇(1-4)、β-谷甾醇(15)、osmanthuside J(16)、luteolin4′Oβglucopyranoside (17)、苯甲酸(18)、酪醇(19)。化合物13、16、17为首次从石梓皮中分离得到。从接骨草得到:熊果酸(21)、 肉豆蔻酸(22)、齐墩果酸(23)、莨菪亭(24)、胡萝卜苷(25)、3′,5二羟基4′甲氧基黄酮7OαL鼠李糖基(1→6)βD葡萄糖苷(26)、绿原酸(27)、 麦芽糖(28)、槲皮素(29)、 脑苷脂(210)、3βhydroxylup12en28oic acid(211)、α,β香树素(212)、烟花苷(213)、1Hindole3carboxylic acid (214)、木犀草素(215)、阿魏酸 (216)、ntritetracontan5αol(217)。其中化合物26、28、210、211、213、214、217均为首次从接骨草中分离得到。

关键词: 石梓皮, 接骨草, 傣药, 化学成分

Abstract: Nine and seventeen compounds were isolated from bark of Gmelina arborea and Sambucus chinensis respectively.Compounds from Gmelina arborea were identified by physicochemical data and spectral analysis as apigenin (11),palmitic acid (12),specioside 6′OαDgalactopyranoside (13),stigmasterol (14),βsitosterol (15),osmanthuside J (16),luteolin4′Oβglucopyranoside (17),benzoic acid (18),tyrosol (19).Compounds 13,16,17 were obtained from Gmelina arborea for the first time.Compounds from Sambucus chinensis were identified as ursolic acid (21),teradecanoic acid (22),oleanolic acid (23),scopoletin (24),daucosterol (25),3′,5dyhydroxy4′methoxy flavone7OαLrhamnosyl(1→6)βDglucoside (26),chlorogenic acid (27),maltose (28),quercetin (29),cerebroside (210),3βhydroxylup12en28oic acid (211),α,βamyrin (212),nicotiflorin (213),1Hindole3carboxylic acid (214),luteolin (215),ferulic acid (216),ntritetracontan5αol (217).Compounds 26,28,210,211,213,214,217 were obtained from Sambucus chinensis for the first time.

Key words: barks of Gmelina arborea, Sambucus chinensis, Dai Medicine, chemical constituents