天然产物研究与开发 ›› 2018, Vol. 30 ›› Issue (11): 1943-1949.doi: 10.16333/j.1001-6880.2018.11.016

• 开发研究 • 上一篇    下一篇

百合药材、种植土壤及灌溉水中农药及重金属残留分析

袁志鹰1,2,3,张梦通1,陈乃宏1,2,谢舒平4,裴刚1,2*,黄惠勇1,3*,邓湘波5   

  1. 1湖南中医药大学;2湖南省中药饮片标准化及功能工程技术研究中心;3湖南省药食同源功能性食品工程技术研究中心,长沙 410208;4南京中医药大学,南京 210046;5郴州市食品药品检验检测中心,郴州 423000  
  • 出版日期:2018-12-03 发布日期:2018-12-03
  • 基金资助:

    国家中医药管理局科研项目(ZYBZH-Y-HUN-24);长沙市科技局重点项目(K1406032-11);国家自然科学基金青年项目(81403206);湖南省中药饮片标准化及功能工程技术研究中心开放基金(2018-02)

Analysis of Pesticide and Heavy Metal Residues in Lilium Lancifolium Thunb.,Soil and Irrigation Water

YUAN Zhi-ying1,2,3, ZHANG Meng-tong1, CHEN Nai-hong1,2, XIE Shu-ping4, PEI Gang1,2* , HUANG Hui-yong1,3*, DENG Xiang-bo5   

  1. 1Hunan University of Chinese Medicine; 2Hunan Engineering Technology Center of Standardization and Function of Chinese Herbal Decoction Pieces; 3Hunan Engineering Technology Center of Functional Food Homology of Medicine,Changsha 410208,China; 4Nanjing University of Chinese Medicine,Nanjing 210046,China; 5Chenzhou Center for Food and Drug Control,Chenzhou 423000,China
  • Online:2018-12-03 Published:2018-12-03

摘要: 对湘产药食两用植物卷丹百合的鲜药、干燥药材、产地土壤及灌溉水的安全性进行评价。采用气相色谱法对总六六六、总滴滴涕、甲氰菊酯、毒死蜱、百菌清进行测定,并用AFS-AAS法测定As、Hg、Pb、Cd、Cr和Cu含量。结果显示,6个采样区的土壤、灌溉水中六六六、滴滴涕、甲氰菊酯、毒死蜱均未见残留,百菌清残留量为ND~0.126 mg/kg;在百合鲜药、干燥药材中,六六六、滴滴涕、甲氰菊酯、毒死蜱、百菌清5种农药均未测出有残留,另除G-1、D-4样品中Cd残留量超标外,所有样品重金属均符合《植物和制剂对外贸易和贸易的绿色贸易标准》(WM/T2-2004)。根据污染指数评价,龙山具有优良的卷丹百合产地环境,适合生产符合现代质量要求的绿色百合。但研究发现百合对于土壤中镉的富集系数好,有必要加强百合主产区土壤改性进一步研究。

关键词: 百合, 农药, 重金属, 安全评价

Abstract: To evaluate the safety of fresh,dry bulbs of Lilium lancifolium Thunb.,soil and irrigation water of Lilium lancifolium Thunb.Base,gas chromatography was used to determine BHC,DDT,fenpropathrin,chlorpyrifos and chlorothalonil.Meanwhile,the content of As,Hg,Pb,Cd,Cr and Cu was determined by AFS-AAS.In 6 Lilium lancifolium Thunb.bases,BHC,DDT,fenpropathrin,chlorpyrifos of the soil,irrigated water were not detected,and chlorpyrifos remained at ND-0.126 mg/kg.The 5 pesticides were not detected in fresh and dry medicinal herbs.In the Lilium lancifolium Thunb.samples of 6 sampling areas,all the heavy metals in the samples were in accordance with the green trade standard for foreign trade and trade in medicinal plants and preparations (WM/T2-2004) except samples of G-1 and D-4 which exceeded the standard of the residual content of Cd.Accordig to the evaluation of pollution index of heavy metals in the soil and water samples,Longshan couty has excellent environment,suitable for the production of green Lilium lancifolium Thunb.It further confirms that standardized agricultural management makes high quality medicinal materials.However,it was found that the enrichment coefficient of Cd in soil was good.So it is necessary to strengthen the study of soil modification in the main producing area of Lilium lancifolium Thunb.for producing high quality medicinal materials.

Key words: Lilium lancifolium Thunb., pesticides, heavy metals, safety assessment

中图分类号: 

R931.2