天然产物研究与开发 ›› 2015, Vol. 27 ›› Issue (1): 63-66.doi: 10.16333/j.1001-6880.2015.01.013

• 研究简报 • 上一篇    下一篇

水栀子果实化学成分研究(II)

余绍福,周兴栋,邹惠亮,程淼,刘百联,张英,周光雄*   

  1. 暨南大学药学院中药及天然药物研究所,广州 510632
  • 出版日期:2015-01-31 发布日期:2015-02-12

Chemical Constituents in the Fruits of Gardenia jasminoides var. radicans (II)

YU Shao-fu, ZHOU Xing-dong, ZOU Hui-liang, CHENG Miao, LIU Bai-lian, ZHANG Ying, ZHOU Guang-xiong*   

  1. Institute of Traditional Chinese Medicine and Natural Products,College of Pharmacy,Jinan University,Guangzhou 510632,China
  • Online:2015-01-31 Published:2015-02-12

摘要: 利用多种色谱学技术从水栀子Gardenia jasminoides var. radicans果实中分离得到11个化合物,并应用多种波谱学手段将它们的结构分别鉴定为Z-甲基-6-氧代-Z,4-庚二烯酸-O-β-D-龙胆二糖苷(1)、jasminoside O(2)、3,5-二甲氧基-4-羟基-苯甲醛(3)、5-羟甲基糠醛(4)、(5R,2E)-5-羟基-2-甲基-庚-2-烯-1,6-二酮(5)、1-O-对香豆酰基葡萄糖苷(6)、6,7-二甲氧基-4-羟基-1-萘甲酸(7)、10-O-E-p-香豆酰京尼平苷酸(8)、6′′-O-反式-肉桂酰基京尼平龙胆二糖苷(9)、丁香脂素(10)、松脂素(11)。以上化合物均为首次从该植物中分离得到。

关键词: 水栀子, 果实, 化学成分

Abstract: Eleven compounds were isolated from the fruits of Gardenia jasminoides  var.radicans by different chromatographic methods,and their structures were elucidated by spectroscopic characteristics and identified as Z-methyl-6-OXD-Z,4-heptadienoic acid-O-β-D-gentiobioside(1),jasminoside O (2),3,5-dimethoxy-4-hydroxy-benzaldehyde (3),5-hydroxymethyl furfural (4),(5R, 2E)-5-hydroxy-2-methyl-hepta-2-ene-1,6-dione (5),1-O-p-coumaroy1-β-D-glucopyranose (6), 6,7-dimethoxy-4-hydroxy-1-naphthoic acid (7),10-O-E-p-coumaroyl geniposidic acid (8),6″-O-trans-cinnamoyl genipin gentiobioside (9),syringaresinol (10) and pinoresinol (11).All the eleven compounds were isolated from the fruits of G. jasminoides for the first time.

Key words: Gardenia jasminoides var.radicans, fruits, chemical constituents

中图分类号: 

R284.2