天然产物研究与开发 ›› 2017, Vol. 29 ›› Issue (6): 971-975.doi: 10.16333/j.1001-6880.2017.6.012

• 研究简报 • 上一篇    下一篇

D-101大孔吸附树脂吸附构树叶总黄酮的研究

汪雁1*,徐荣华1,彭林彩2,王春芳1,唐家杨1   

  1. 1 安徽科技学院生命科学学院,凤阳 233100;2 四川文理学院化学化工学院,达州 635000
  • 出版日期:2017-06-30 发布日期:2017-07-06

Adsorption Study of Total Flavonoids from Broussonetia papyrifera Leaves by D-101 Macroporous Adsorption Resin

WANG Yan1*,XU Rong-hua1,PENG Lin-cai2,WANG Chun-fang1,TANG Jia-yang1   

  1. 1 College of Life Sciences,Anhui Science and Technology University,Fengyang 233100,China; 2 School of Chemistry and Chemical Engineering,Sichuan University of Arts and Science,Dazhou 635000,China
  • Online:2017-06-30 Published:2017-07-06

摘要: 本论文通过研究大孔树脂对构树叶黄酮吸附过程中动力学与热力学的变化,寻找大孔吸附树脂对该体系吸附能力的规律。结果表明,大孔吸附树脂对构树叶黄酮的吸附在9 h后达到平衡,且吸附过程符合二级动力学方程;不同温度下该大孔吸附树脂对构树叶黄酮的吸附等温线采用Freundlich和Langmuir等温吸附方程进行拟合,结果与Freundlich等温吸附模型拟合度较高,说明该吸附为优惠吸附,同时吸附焓变ΔH<0、吸附自由能ΔG<0、吸附熵变ΔS>0,说明大孔吸附树脂对构树叶黄酮的吸附过程是放热的,该吸附过程为自发不可逆过程,且吸附有明显的物理吸附特性。

关键词: D-101大孔吸附树脂, 构树叶, 黄酮, 吸附动力学和热力学

Abstract: The dynamics and thermodynamics model about the process of macroporous resin adsorption for flavonoids in Broussonetia papyrifera leaves extracts has not been reported.In order to find the law of the process,this study investigated the adsorption kinetics and thermodynamics behavior of flavonoids in B. papyrifera leaves extracts on D-101 type macroporous adsorption resin.The results showed that the macroporous resin adsorption process for flavonoids in B.papyrifera leaves extracts reached balance after 9 hours.The adsorption fitted with the pseudo-second-order kinetic model.Static adsorption isotherms at different temperatures illustrated that the process of adsorption for flavonoids in B.papyrifera leaves extracts was well fitted by Freundlich-type isotherm equation and the adsorption was favorable type.ΔH<0,ΔG<0 and ΔS>0 indicated that the adsorption was an exothermic process and enthalpy promoting process.

Key words: D-101 macroporous adsorption resin, Broussonetia papyrifera leaves, flavonoids, adsorption dynamics and thermodynamics