石菖蒲的化学成分研究

天然产物研究与开发 ›› 2011, Vol. 23 ›› Issue (3): 404-409.

石菖蒲的化学成分研究

仝晓刚1,2，程永现1*

¹中国科学院昆明植物研究所植物化学与西部植物资源持续利用国家重点实验室，昆明 650204；²中国科学院研究生院，北京 100049

收稿日期:2010-08-23 出版日期:2011-06-25 发布日期:2011-08-08
通讯作者: yxcheng@mail.kib.ac.cn
基金资助:
中国科学院知识创新重要方向项目（KSCX2-YW-R-118 和 KSCX2-YW-R-211）；中国科学院昆明植物研究所植物化学与西部植物资源持续利用国家重点实验室自主课题项目（P2008-ZZ11）；云南省中青年学术技术带头人与后备人才项目（No. 2007PY01-48）；国家十一五科技部重大新药创制项目（2008ZX09401-004）

Chemical Constituents from Acorus tatarinowii

TONG Xiao-gang^1,2, CHENG Yong-xian^1*

¹State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, The Chinese Academy of Sciences, Kunming 650204, China; ²Graduate School of the Chinese Academy of Sciences, Beijing 100049, China

Received:2010-08-23 Online:2011-06-25 Published:2011-08-08

摘要/Abstract

摘要：

运用色谱法从石菖蒲根茎提取物中分离得到18个化合物，经波谱学分析鉴定为：(7S,8R)-4,9′-dihydroxyl-3,3′-dimethoxyl-7,8-dihydrobenzofuran-1′-propylneoliga（1），(7S,8R)-4,9′-dihydroxyl-3,3′-dimethoxyl-7,8-dihydrobenzofuran -1′-propylneoligan-9-O-β-d-glucopyranoside（2），7′-hydroxylariciresinol-9-acetate（3），5-羟基-3,7,4′-三甲氧基黄酮（4），野漆树苷（5），紫云英苷（6），松属素-3-O-芸香糖苷（7），山奈酚-3-O-芸香糖苷（8），德钦红景天苷（9），isoschaftoside（10），5-羟甲基糠醛（11），反式桂皮酸（12），3,7-dihydroxy-11,15,23-trioxo-lanost-8,16-dien-26-oic（13），3,7-dihydroxy-11,15,23-trioxo-lanost-8,16-dien-26-oic acid methyl ester（14），环阿屯醇（15），胡萝卜苷（16），羽扇豆醇（17），(22E,24R)-ergosta-5,7,22-trien-3β-ol（18）。除化合物4、11和16外，其余15个化合物均为首次从该植物中分离得到。

关键词: 石菖蒲, 天南星科, 酚性成分, 三萜

Abstract:

Eighteen compounds were isolated from the rhizome of Acorus tatarinowii. Their structures were identified by spectroscopic data as (7S, 8R)-4,9′-dihydroxyl-3,3′-dimethoxyl-7,8-dihydrobenzofuran-1′-propylneoliga (1), (7S,8R)-4,9′-dihydroxyl-3,3′-dimethoxyl-7,8-dihydrobenzofuran-1′-propylneoligan-9-O-β-d-glucopyranoside (2), 7′-hydroxylariciresinol-9-acetate (3), 5-hydroxy-3,7,4′-trimethoxyflavone (4), rhoifolin (5), astragalin (6), pinocembrin-7-O-rutinoside (7), kaempferol-3-rutinoside (8), rhodionin (9), isoschaftoside (10), 5-hydroxymethyl-2-furaldehyde (11), trans-cinnamic acid (12), 3,7-dihydroxy-11,15,23-trioxo-lanost-8,16-dien-26-oic (13), 3,7-dihydroxy-11,15, 23-trioxo-lanost-8,16-dien-26-oic acid methyl ester (14), cycloartenol (15), daucosterol (16), lupeol (17), (22E,24R)-ergosta-5,7,22-trien-3β-ol (18). Except for compounds 4, 11, and 16, all the other substances were obtained from this plant for the first time.

Key words: Acorus tatarinowii, Araceae, phenols, triterpenoids

中图分类号:

R284.2 R946

仝晓刚，程永现. 石菖蒲的化学成分研究[J]. 天然产物研究与开发, 2011, 23(3): 404-409.

TONG Xiao-gang, CHENG Yong-xian. Chemical Constituents from Acorus tatarinowii[J]. NATURAL PRODUCT RESEARCH AND DEVELOPMENT, 2011, 23(3): 404-409.

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